21: Reactions of Radicals Produced by Electron Transfer to Manganese(III) Acetate & Ammonium Cerium(IV) Nitrate
- Page ID
- 24632
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Manganese(III) acetate and ammonium cerium(IV) nitrate each react with CH-acidic compounds to produce carbon-centered radicals.1–12 These radicals add preferentially to compounds with electron-rich multiple bonds. The role of a carbohydrate in a reaction of this type is to provide the multiple bond to which addition occurs.