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ChemWiki: The Dynamic Chemistry E-textbook > Development Details > Approaches > Demos > Additional Demos > Chemiluminescence-- Singlet Oxygen

Chemiluminescence-- Singlet Oxygen

Chemical Concepts Demonstrated

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Demonstration 

  • A: Cl2 Cylinder
  • B and C: Gas washing bottles
  • E: 30% H2O2 and 6M NaOH
  • F: 6M NaOH

Open the main valve on the Cl2 cylinder. 

Observations

A red glow will be observed.

Explanation (including important chemical equations)

The red glow is caused by the formation and decay of singlet O2.

Cl2 + H2O2 --(OH-)--> O2 + 2 HCl (the oxygen formed here is singlet oxygen)

Singlet oxygen is an excited form of oxygen.  Oxygen normally has two unpaired electrons in its outermost orbital.  Upon receiving this exitation, the two electrons occupy a single molecular orbital. Two singlet oxygens go to the ground state by a two molecule, one photon transition.  This is actually a form of radioactive decay, and it causes the red glow.

2 O2(1Dg) -> 2 O2(3Sg) + hv (630 nm)

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Last Modified
10:28, 2 Oct 2013

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