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ChemWiki: The Dynamic Chemistry E-textbook > Inorganic Chemistry > Descriptive Chemistry > d-Block Elements > The Iron Triad: Iron, Cobalt, and Nickel

The Iron Triad: Iron, Cobalt, and Nickel

The Iron Triad is composed of three elements: iron (Fe), cobalt (Co), and nickel (Ni), which share similar chemical and physical characteristics. They are found adjacent to each other in period 4 of the periodic table.

Introduction

The Iron Triad is known for possessing ferromagnetic elements similar to gadolinium (Gd), and neodymium (Nd). These types of ferromagnetic elements have the ability to create a large magnetic pole due to their unpaired electrons. When one of these elements is inside an environment where the temperature is at its individual Curie Point (Tc), however, the specific paramagnetic lining of atoms is broken down by the energy within the element and ferromagnetism is lost. The (Tc)'s for iron, cobalt, and nickel are 768°C, 1121°C, and 354°C respectively and are taken advantage of to make use of these elements in industry.  In addition, elements in the iron triad are commonly combined with carbon and each other to create various types of alloys.  It is because of these magnetic properties and use in alloys that the three elements are typically grouped together and labeled as the "Iron Triad".

While very similar in magnetic properties and reaction, these elements are also very unique and used differently in both nature and industry.

Iron

Iron (Fe) is a transition metal with an atomic weight of 55.845 and an atomic number of 26. Its most common and comfortable oxidation state is +3 and is usually a shiny silver color. While it can be found in the sun and the stars, it is extremely common on planet earth and its abundance in the earth’s crust is 4.7%. The pure metal form of iron is rarely found due to its ability to easily react with other metals and environments.

IRON.jpg

Applications of Iron

Iron's most common use in worldwide industry is to be used in alloys and steels for everyday use, some which even contain other elements in the Triad.  By combining metals like iron with carbon to make alloys, very strong materials can be made that are used for steel housings, supports in television tubes, and other important products.  Pure iron is available commercially in the United States and production of about 500 million tons of Iron is created every year throughout the world.

From a biological perspective, iron is essential to organisms since it’s needed for the creation of hemoglobin. Humans need hemoglobin since these red pigments supply oxygen to our body through red blood cells. To increase intake of iron, foods like eggs, groundnuts and green leafy vegetables should be consumed. Without iron, our bodies would not be able to form hemoglobin and an organism would fail to survive.

tv.jpg                egg.jpg

 

Cobalt

Cobalt (Co) is a transition metal with an atomic weight of 58.93 and an atomic number of 27, right in between iron and nickel. Cobalt, however, is not as abundant as iron and only makes up of about 0.0020% of the Earth’s crust.  This makes cobalt a little more rare and valuable than the other members of the triad because it is still used heavily in international industry.  It is for this reason that this hard gray element is mined for and traded around the world.

cobalt.jpg

Applications of Cobalt

Like iron, this element is commonly combined with other metals to create alloys. Superalloys that contain cobalt are used for parts of gas turbine engines that benefit both commercial and military devices.  In current times, however, the rise of rechargeable batteries has made demand for the element rise to new heights since it is commonly used for electrodes in this relatively new technology.  While these are its most popular applications, cobalt is also utilized in the production of petroleum, dyes, magnets, and electronics due to its ferromagnetic properties.

Cobalt and its alloys have recently made strides in the biomedical sphere by playing a large role in neurological, dental, orthopedic, and cardiovascular implant devices.  This is due to the fact that the alloys function well with their corrosion resistance, mechanical properties, and biocompatibility.

jet engine.jpg                             ortho.jpg

Nickel

Nickel (Ni), a transition metal with an atomic weight of 58.69 and an atomic number of 28, is usually recognized by its silvery shine with a hint of gold color. It was first discovered by Axel Fredrik Cronstedt in 1751 and named nickel from the ore "kupfernickel". Although nickel is not extremely common, it still ranks as #24 on the list of the most abundant elements on earth.

nickel.jpg

Applications of Nickel

This element is most abundant in Canada and about 300 million pounds are used in America every year. Nickel is most commonly used as a key ingredient in low alloy steels, stainless steels, and cast irons.  In fact, four out of five of these 300 million pounds of Nickel go to this type of alloy making.  Like cobalt, it shares the unique characteristic of corrosion resistance and is ideal for corrosion and heat resistant coatings, magnetic alloys, and controlled-expansion alloys.

New nickel-cadmium rechargeable batteries have also brought the use of nickel into a new light.  Like cobalt, the turning of the millennium and the increased use of rechargeable batteries has given nickel a new major use that will likely surpass others in the future.  Nickel-cadmium batteries have improved the performance of cordless power tools, portable computers, and other portable electronic devices.

battery.jpg                                          drill.jpg

 

Chemical Properties of Iron Triad Elements

 

 

Iron

Cobalt

Nickel

Atomic Number

26

27

28

Mass

55.85

58.93

58.69

Electron Configuration

3d64s2

3d74s2

3d84s1

Metallic radius, pm

124

125

125

Ionization Energy, kJ mol-1

 762.5

 

 760.4

 

 737.1

 

-          First

759

758

737

-          Second

1561

1646

1753

-          Third

2957

3232

3393

E°, Vb

-0.440

-0.277

-0.257

Common (+) Oxidation States

2, 3, 6

2, 3

2, 3

Melting Point (°C)

1530

1495

1455

Boiling Point (°C)

2862

2927

2732

Density, g cm-3

7.87

8.90

8.91

Electrical Conductivitye

16

25

23

Practice Problems

1.       Fe2O3(s) + 3CO(g) --> 2Fe (l) + 2CO2(g)

2.         5Fe2+(aq) + MnO4-(aq) + 8H+(aq) --> 5Fe3+(aq) + Mn2+(aq) +4H2O(l)

3.       [Fe(H2O)6]3+ +SCN-(aq) --> [FeSCN(H2O)5]2+ + H2O(l)

4.       4FeS + 7O2 --> 2Fe2O3 + 4SO2

5.       Ni + H2O --> No Reaction

References

  1. Cracolice,Mark S. and Peters, Edward I.  - Introductory Chemistry: An Active Learning Approach
  2. John A. Disegi, Richard L. Kennedy, Robert Pilliar - Cobalt-Base Alloys for Biomedical Applications
  3. Joseph R. Davis, ASM International - ASM Specialty Handbook: Nickel, Cobalt, and Their Alloys
  4. Kim B. Shedd - The United States Geological Survey 2006 Minerals Yearbook
  5. Petrucci, Harwood, Herring, and Madura - General Chemistry 9th Edition
  6. Walter H. Kohl - Handbook of Materials and Techniques for Vacuum Device
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Last Modified
16:17, 6 Oct 2014

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