IV. Thermally Generated Radicals
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- 23814
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Heating of carbohydrates has a limited role in causing useful radical reactions. Few carbohydrates or their derivatives have bonds weak enough to generate radicals at temperatures that avoid general structural decomposition. As described earlier in this chapter, a carbohydrate derivative with a carbon–cobalt or oxygen-iodine bond can generate radicals by thermal reaction, but even for such compounds radical formation usually takes place photochemically.