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IV. Thermally Generated Radicals

  • Page ID
    23814
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    Heating of carbohydrates has a limited role in causing use­ful radical reactions. Few carbo­hy­drates or their derivatives have bonds weak enough to generate radi­cals at temperatures that avoid general structural decom­po­sition. As described earlier in this chapter, a carbohydrate deriva­tive with a carbon–cobalt or oxygen-iodine bond can generate radicals by thermal reac­tion, but even for such compounds radical formation usually takes place photo­chemically.


    This page titled IV. Thermally Generated Radicals is shared under a All Rights Reserved (used with permission) license and was authored, remixed, and/or curated by Roger W. Binkley and Edith R. Binkley.

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