V. Stereoselectivity in Synthesis
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- 23961
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The primary thrust of the discussion in this chapter is to understand the factors controlling stereoselectivity in radical reactions. Many of the reactions examined provide both basic understanding of radical-reaction stereoselectivity and examples of how stereoselectivity can achieve a particular synthetic goal. The emphasis in discussion in this part of the chapter shifts to reactions where the primary goal is to solve a particular synthetic problem by taking advantage of knowledge about stereoselectivity in radical reactions. Even though the purpose in conducting these reactions is synthetic, their investigation has increased basic understanding of radical-reaction stereoselectivity.