III. Alkylthio and Arylthio Substituted Carbohydrates and Related Compounds
- Page ID
- 24010
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The identity of the carbon–sulfur single bond broken during reaction of a carbohydrate that has two such bonds depends upon the stability of the carbon-centered radical being formed. If the sulfur atom is part of a methylthio,8–11 ethylthio,12–15 or arylthio15–24 group, radical stability favors producing a carbohydrate radical rather than a methyl, ethyl, phenyl, or p-tolyl radical (Scheme 6).
