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II. Alkoxy Radicals

  • Page ID
    24031
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    Although oxygen-centered radicals are not formed in significant number by direct hydrogen-atom abstraction from carbohydrates, these radicals can be produced indirectly in high yield from carbo­hydrate derivatives. Since such radicals are capable of internal reaction, intramolecular abstraction provides a pathway for oxygen-centered radicals to produce specific, carbon-centered radicals and, in so doing, to participate in synthe­tically useful reactions. (Alkoxy and alkoxyl are both terms used in describing oxygen-centered radicals derived from alcohols. The alkoxy designation will be used here.)


    This page titled II. Alkoxy Radicals is shared under a All Rights Reserved (used with permission) license and was authored, remixed, and/or curated by Roger W. Binkley and Edith R. Binkley.

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