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V. Reactions of Carbonyl-Conjugated Radicals

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    24037
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    In addition to dimerization (eq 12) carbonyl-conjugated radicals also can be reduced to an­ions in a pH-dependent reduction by Ti3+ (eq 13).30 At pH 1 the reaction shown in eq 13 is neg­li­gible, but at pH 7 this reaction becomes an important pathway for removing carbonyl-conjugated radicals from a reaction mixture.30

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    This page titled V. Reactions of Carbonyl-Conjugated Radicals is shared under a All Rights Reserved (used with permission) license and was authored, remixed, and/or curated by Roger W. Binkley and Edith R. Binkley.