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12: Reactions of O-Thiocarbonyl Compounds

  • Page ID
    24071
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    Reaction of an O-thiocarbonyl derivative of a carbohydrate with a tin- or silicon-centered radical generates a carbon-centered radical that undergoes reactions typical of such an inter­mediate. These reactions include abstracting a hydrogen atom from a donor molecule (almost always a tin or silicon hydride), adding to a compound containing a multiple bond, or forming a new ring system by adding internally to a multiple bond within the radical. These reactions place O‑thiocarbonyl compounds among the most useful substrates for radical formation from carbo­hy­­drates. The current chap­ter, where the reactions of these compounds are discussed, is a close com­­panion to the preceding one (Chapter 11), where synthesis of O-thio­carbonyl carbo­hy­drate derivatives is described.


    This page titled 12: Reactions of O-Thiocarbonyl Compounds is shared under a All Rights Reserved (used with permission) license and was authored, remixed, and/or curated by Roger W. Binkley and Edith R. Binkley.

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