VI. Generating Methyl Radicals
- Page ID
- 24082
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Photolysis of acetylated N-hydroxypyridine-2-thione produces a methyl radical (Scheme 6).52 Methyl radicals generated in this way react with tellurium-containing nucleosides to generate the corresponding, carbon-centered radicals.52–56 In the reaction shown in Scheme 6, radical formation from photolysis of O-acetyl-N-hydroxypyridine-2-thione is the first step in producing a new ring system.52
