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Main pages
ChemWiki: The Dyna...
Inorganic Chemistry
Case Studies
Coordination Chemis...
Crystal Field Theory
Descriptive Chemistr...
Electronic Configura...
Lattices
Ligand Field Theory
Molecular Geometry
Organometallic Chem...
Fundamentals
Introduction to Orga...
Ligands
Structural Fundamen...
Reactions in Aqueou...
Organometallic Chemistry
Table of contents
1.
Introductions
2.
Structural Fundamentals
3.
Ligand Survey
4.
Fundamental Reactions & Steps
5.
Contributors
Case Studies
v
Case Study: Contrasting Earth, Mars and the Moon's Atmospheres
Case Study: Elemental Toxicity in Animals
Case Study: The Natural Abundance of Elements in the Earth & Universe
Case Study: Water Treatment
Coordination Chemistry
v
Basics of Coordination Chemistry
Complex Ion Equilibria
Coordination Numbers
Isomers
Ligands
Crystal Field Theory
v
Colors of Coordination Complexes
Crystal Field Theory
High Spin and Low Spin Complexes
Metals, Tetrahedral and Octahedral
Tanabe-Sugano Diagrams
Virtual: Electronic Structure
Descriptive Chemistry
v
Compounds
Introduction to Elements
Main Group Elements
Periodic Table of the Elements
Transition Metals and Coordination Complexes
Electronic Configurations
v
Aufbau Principle
Electron Configuration of Transition Metals and Ions: Mn vs. Cu
Hund's Rules
Pauli Exclusion Principle
Spin Pairing Energy
Lattices
v
Lattice Energy: The Born-Haber cycle
Schottky Defect
The Born-Lande' equation
Ligand Field Theory
v
Ligand Field Theory Fundamentals
Virtual: Ligand Field Theory
Molecular Geometry
v
Bent Molecular Geometry
Case Studies
Limitations of VSEPR
Linear Molecular Geometry
Octahedral
Square Planar
Square Pyramidal
Tetrahedral Molecular Geometry
Trigonal Planar Molecular Geometry
Trigonal Pyramid Molecular Geometry
T-shaped
Virtual: Isomerization
VSEPR
Organometallic Chemistry
v
Fundamentals
Introduction to Organometallic Chemistry
Ligands
Structural Fundamentals
Reactions in Aqueous Solutions
v
Precipitation Reactions
Unique Features of Aqueous Solutions
Introductions
What is Organometallic Chemistry?
Resources for Organometallic Chemistry
Structural Fundamentals
Simplifying the Organometallic Complex 1
·
2
·
3
Periodic Trends of the Transition Metals
Predicting the Geometry of Organometallic Complexes
Ligand Field Theory & Frontier Molecular Orbital Theory
Coordinative Unsaturation
Ligand Survey
Carbon Monoxide
Phosphines
N
-heterocyclic Carbenes
π
Systems 1 · 2
Carbenes
Dative Ligands of N, O, and S
Hydrides
Alkyls 1 · 2 · 3
Odd-numbered
π
Systems
σ Complexes
Fundamental Reactions & Steps
The
trans
Effect
Ligand Substitution: General Ideas
Associative Ligand Substitution
Dissociative Ligand Substitution
Other Ligand Substitutions
Oxidative Addition: General Ideas
Oxidative Addition of Non-polar Reagents
Oxidative Addition of Polar Reagents (
coming soon
!
)
Contributors
Michael Evans (
http://www.metallacycle.com
)
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