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This is the first semester in a two-semester introductory course focused on current theories of structure and mechanism in organic chemistry, their historical development, and their basis in experimental observation. J. Michael McBride is the Richard M. Colgate Professor of Chemistry at Yale University.
|1. How Do You Know?|
|2. Force Laws, Lewis Structures and Resonance|
|3. Double Minima, Earnshaw's Theore...|
|4. Coping with Smallness and Scanning Probe...|
|5. X-Ray Diffraction|
|6. Seeing Bonds by Electron Difference Density|
|7. Quantum Mechanical Kinetic Energy|
|8. One-Dimensional Wave Functions|
|9. Chladni Figures and One-Electron Atoms|
|10. Reality and the Orbital Approximation|
|11. Orbital Correction and Plum-Pudding Molecules|
|12. Overlap and Atom-Pair Bonds|
|13. Overlap and Energy-Match|
|14. Checking Hybridization Theory with XH3|
|15. Chemical Reactivity: SOMO, HOMO...|
|16. Recognizing Functional Groups|
|17. Reaction Analogies and Carbonyl Reactivity|
|18. Amide, Carboxylic Acid and Alkyl Lithium|
|19. Oxygen and the Chemical Revolution...|
|20. Rise of the Atomic Theory (1790-1805)|
|21. Berzelius to Liebig and Wöhler...|
|22. Radical and Type Theories (1832-1850)|
|23. Valence Theory and Constitutional Structure...|
|24. Determining Chemical Structure by Isomer...|
|25. Models in 3-D Space (1869-1877); Optical...|
|26. Van't Hoff's Tetrahedral Carbon and Chirality|
|27. Communicating Molecular Structure...|
|28. Stereochemical Nomenclature...|
|29. Preparing Single Enantiomers and...|
|30. Esomeprazole as an Example of Drug...|
|31. Preparing Single Enantiomers and...|
|32. Stereotopicity and Baeyer Strain...|
|33. Conformational Energy and...|
|34. Sharpless Oxidation Catalysts...|
|35. Understanding Molecular Structure...|
|36. Bond Energies, the Boltzmann Factor...|
|37. Potential Energy Surfaces...|
An NSF funded Project