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ChemWiki: The Dynamic Chemistry E-textbook > Physical Chemistry > Equilibria > Chemical Equilibria > Reversible vs. Irreversible Reactions

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Reversible vs. Irreversible Reactions

Reversible and irreversible reactions are prevalent in nature and are responsible for reactions such as the breakdown of ammonia.

Introduction

It was believed that all chemical reactions were irreversible until 1803, when French chemist Claude Louis Berthollet introduced the concept of reversible reactions. Initially he observed that sodium carbonate and calcium chloride react to yield calcium carbonate and sodium chloride; however, after observing sodium carbonate formation around the edges of salt lakes, he realized that large amount of salts in the evaporating water reacted with calcium carbonate to form sodium carbonate, indicating that the reverse reaction was occurring. 

Chemical reactions are represented by chemical equations. These equations typically have a unidirectional arrow (\(\rightarrow\)) to represent irreversible reactions. Other chemical equations may have a bidirectional harpoons (\(\rightleftharpoons\)) that represent reversible reactions (not to be confused with the double arrows \(\leftrightarrow\) used to indicate resonance structures). To review the fundamentals of chemical reactions, click here: Chemical Reactions

Irreversible Reactions

A fundamental concept of chemistry is that chemical reactions occurred when reactants reacted with each other to form products. These unidirectional reactions are known as irreversible reactions, reactions in which the reactants convert to products and where the products cannot convert back to the reactants. These reactions are essentially like baking. The ingredients, acting as the reactants, are mixed and baked together to form a cake, which acts as the product. This cake cannot be converted back to the reactants (the eggs, flour, etc.), just as the products in an irreversible reaction cannot convert back into the reactants. 

An example of an irreversible reaction is combustion. Combustion involves burning an organic compound—such as a hydrocarbon—​and oxygen to produce carbon dioxide and water. Because water and carbon dioxide are stable, they do not react with each other to form the reactants. Combustion reactions take the following form:

\[ C_xH_y + O_2 \rightarrow CO_2 + H_2O \]

Reversible Reactions

In reversible reactions, the reactants and products are never fully consumed; they are each constantly reacting and being produced. A reversible reaction can take the following summarized form:

\[ A + B \underset{k_{-1}} {\overset{k_1} {\rightleftharpoons}} C + D \]

This reversible reaction can be broken into two reactions.

Reaction 1: 

\[ A + B \xrightarrow{k_1}C+D \]

Reaction 2:

 \[ C + D \xrightarrow{k_{-1}}A+B \]

These two reactions are occurring simultaneously, which means that the reactants are reacting to yield the products, as the products are reacting to produce the reactants. Collisions of the reacting molecules cause chemical reactions in a closed system. After products are formed, the bonds between these products are broken when the molecules collide with each other, producing sufficient energy needed to break the bonds of the product and reactant molecules. 

Below is an example of the summarized form of a reversible reaction and a breakdown of the reversible reaction N2O4 ↔ 2NO2

Reaction 1 and Reaction 2 happen at the same time because they are in a closed system.

Blue: Nitrogen    Red: Oxygen 

                                            Reaction 1                                                                                            Reaction 2

Reversible reaction.jpg

Imagine a ballroom. Let reactant A be 10 girls and reactant B be 10 boys. As each girl and boy goes to the dance floor, they pair up to become a product. Once five girls and five boys are on the dance floor, one of the five pairs breaks up and moves to the sidelines, becoming reactants again. As this pair leaves the dance floor, another boy and girl on the sidelines pair up to form a product once more. This process continues over and over again, representing a reversible reaction. 

Unlike irreversible reactions, reversible reactions lead to equilibrium: in reversible reactions, the reaction proceeds in both directions whereas in irreversible reactions the reaction proceeds in only one direction. To learn more about this phenomenon, click here: Chemical Equilibrium

If the reactants are formed at the same rate as  the products, a dynamic equilibrium exists. For example, if a water tank is being filled with water at the same rate as water is leaving the tank (through a hypothetical hole), the amount of water remaining in the tank remains consistent. 

Connection to Biology

There are four binding sites on a hemoglobin protein. Hemoglobin molecules can either bind to carbon dioxide or oxygen. As blood travels through the alveoli of the lungs, hemoglobin molecules pick up oxygen-rich molecules and bind to the oxygen. As the hemoglobin travels through the rest of the body, it drops off oxygen at the capillaries for the organ system to use oxygen. After expelling the oxygen, it picks up carbon dioxide. Because this process is constantly carried out through the body, there are always hemoglobin molecules picking or expelling oxygen and other hemoglobin molecules that are picking up or expelling carbon dioxide. Therefore, the hemoglobin molecules, oxygen, and carbon dioxide are reactants while the hemoglobin molecules with oxygen or carbon dioxide bound to them are the products. In this closed system, some reactants convert into products as some products are changing into reactants, making it similar to a reversible reaction.

References

  1. Zumdahl, Steven S. "Chemical Principles." 6th Ed. Boston: Houghton Mifflin, 2009. 
  2. Petrucci, Ralph H., Harwood, William S., Herring, F. G., and Madura Jeffrey D. "General Chemistry: Principles & Modern Applications." 10th Ed. New Jersey: Pearson Education, Inc., 2011.

Outside Links

Problems

  1. What is the key difference between reversible and irreversible reactions?
  2. Why is combustion an example of an irreversible reaction?
  3. How can a reversible reaction occur?
  4. Is the following hypothetical reaction reversible?                              A+ B → C
  5. Why do irreversible reactions not lead to equilbrium?

Solutions

  1. In a irreversible reaction, the reactants react to form the products, which cannot revert back into reactants. In reversible reactions, as the reactants react with other reactants to form products, the products are reacting with other products to form reactants. 
  2. Combustion cannot be undone.
  3. When the reactant molecules are placed in a closed environment, the reactant molecules will collide with each other, producing energy that can break the bonds between reactant and product molecules. Breaking such bonds will allow the products to become reactants and the reactants to become products. 
  4. No, it is not reversible, as indicated by the unidirectional arrow.
  5. Irreversible reactions only proceed in one direction, so the reaction can never be at equilibrium.

Contributors

  • Heather Yee (UCD), Mandeep Sohal (UCD)

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Last Modified
11:41, 28 May 2014

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