Interesting online CONFCHEM discussion going on right now on the ChemWiki and
greater STEMWiki Hyperlibary project. Come join the discussion.
A catalytic converter is a device used to reduce the emissions from an internal combustion engine (used in most modern day automobiles and vehicles). Not enough oxygen is available to oxidize the carbon fuel in these engines completely into carbon dioxide and water; thus toxic by-products are produced. Catalytic converters are used in exhaust systems to provide a site for the oxidation and reduction of toxic by-products (like nitrogen oxides, carbon monoxide, and hydrocarbons) of fuel into less hazardous substances such as carbon dioxide, water vapor, and nitrogen gas.
Catalytic converters were first widely introduced in American production cars in 1975 due to EPA regulations on toxic emissions reductions. The United States Clean Air Act required a 75% decrease in emissions in all new model vehicles after 1975, a decrease to be carried out with the use of catalytic converters. Without catalytic converters, vehicles release hydrocarbons, carbon monoxide, and nitrogen oxide. These gases are the largest source of ground level ozone, which causes smog and is harmful to plant life. Catalytic converters can also be found in generators, buses, trucks, and trains—almost everything with an internal combustion engine has a form of catalytic converter attached to its exhaust system.
A catalytic converter is a simple device that uses basic redox reactions to reduce the pollutants a car makes. It converts around 98% of the harmful fumes produced by a car engine into less harmful gases. It is composed of a metal housing with a ceramic honeycomb-like interior with insulating layers. This honeycomb interior has thin wall channels that are coated with a washcoat of aluminum oxide. This coating is porous and increases the surface area, allowing more reactions to take place and containing precious metals such as platinum, rhodium, and palladium. No more than 4-9 grams of these precious metals are used in a single converter.
The converter uses simple oxidation and reduction reactions to convert the unwanted fumes. Recall that oxidation is the loss of electrons and that reduction is the gaining of electrons. The precious metals mentioned earlier promote the transfer of electrons and, in turn, the conversion of toxic fumes.
The last section of the converter controls the fuel-injection system. This control system is aided by an oxygen sensor that monitors how much oxygen is in the exhaust stream, and in turn tells the engine computer to adjust the air-to-fuel ratio, keeping the catalytic converter running at the stoichiometric point and near 100% efficiency.
A three-way catalytic converter has three simultaneous functions:
There are two types of "systems" running in a catalytic converter, "lean" and "rich." When the system is running "lean," there is more oxygen than required, and the reactions therefore favor the oxidation of carbon monoxide and hydrocarbons (at the expense of the reduction of nitrogen oxides). On the contrary, when the system is running "rich," there is more fuel than needed, and the reactions favor the reduction of nitrogen oxides into elemental nitrogen and oxygen (at the expense of the two oxidation reactions). With a constant imbalance of the reactions, the system never achieves 100% efficiency.
Note: converters can store "extra" oxygen in the exhaust stream for later use. This storage usually occurs when the system is running lean; the gas is released when there is not enough oxygen in the exhaust stream. The released oxygen compensates for the lack of oxygen derived from NOx reduction, or when there is hard acceleration and the air-to-fuel ratio system becomes rich faster than the catalytic converter can adapt to it. In addition, the release of the stored oxygen stimulates the the oxidation processes of CO and CxH4x.
Without the redox process to filter and convert the nitrogen oxides, carbon monoxides, and hydrocarbons, the air quality (especially in large cities) becomes harmful to the human being.
Nitrogen oxides: These compounds are of the same family as nitrogen dioxide, nitric acid, nitrous oxide, nitrates, and nitric oxide. When NOx is released into the air, it reacts, stimulated by sunlight, with organic compounds in the air; the result is smog. Smog is a pollutant and has adverse effects on children's lungs. NOx reacting with sulfur dioxide produces acid rain, which is highly destructive to everything it lands on. Acid rain corrodes cars, plants, buildings, national monuments and pollutes lakes and streams to an acidity unsuitable for fish. NOx can also bind with ozone to create biological mutations (such as smog), and reduce the transmission of light.
Carbon monoxide: This is a harmful variant of a naturally occurring gas, CO2. Odorless and colorless, this gas does not have many useful functions in everyday processes.
Hydrocarbons: Inhaling hydrocarbons from gasoline, household cleaners, propellants, kerosene and other fuels can be fatal to children. Further complications include central nervous system impairments and cardiovascular problems.
The catalytic converter is a sensitive device with precious metals coating the inside. Without these metals, the redox reactions cannot occur. There are several substances and chemicals that inhibit the catalytic converter.
These contaminants prevent the catalytic converter from functioning properly. However, this process could be reversed by running the engine at a high temperature to increase the hot exhaust flow through the converter, melting or liquefying some of the contaminants and removing them from the exhaust pipe. This process does not work if the metal is coated with lead, because lead has a high boiling point. If the lead poisoning is severe enough, the whole converter is rendered useless and must be replaced.
Recall that thermodynamics predicts whether or not a reaction or process is spontaneous under certain conditions, but not the rate of the process. The redox reactions below occur slowly without a catalyst; even if the processes are thermodynamically favorable, they cannot occur without proper energy. This energy is the activation energy (\(E_a\) in the figure below) required to overcome the initial energy barrier preventing the reaction. A catalyst aids in the thermodynamic process by lowering the activation energy; the catalyst itself does not produce a product, but it does affect the amount and the speed at which the products are formed.
Due to the precious metals in the coating of the inner ceramic structure, many catalytic converters have been targeted for theft. The converter is the most easily-accessible component because it lies on the outside and under the car. A thief could easily slide under the car, saw the connecting tubes on each end, and leave with the catalytic converter. Depending on the type and amount of precious metals inside, a catalytic converter can be easily sold for $200 apiece.
Although the catalytic converter has helped reduce toxic emissions from car engines, it also has detrimental environmental effects. In the conversion of hydrocarbons and carbon monoxide, carbon dioxide is produced. Carbon dioxide is one of the most common greenhouse gases and contributes significantly to global warming. Along with carbon dioxide, the converters sometimes rearrange the nitrogen-oxygen compounds to form nitrous oxide. This is the same compound used in laughing gas and as a speed enhancer in cars. As a greenhouse gas, nitrous oxide is a 300 times more potent than carbon dioxide, and contributes proportionally to global warming.
This material is based upon work supported by the National Science Foundation under Grant Number 1246120