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ChemWiki: The Dynamic Chemistry Hypertext > Physical Chemistry > Quantum Mechanics > 15: Time-dependent Quantum Dynamics

15: Time-dependent Quantum Dynamics

Postulate V states how the *time-dependent* Schrödinger equation describes the evolution of a system’s wavefunction through time.

The Schrödinger equation is the basis for quantum mechanics. The solutions to the equation, known as wave functions, give complete quantum mechanical insight into the system under observation. The Hamiltonian operator, which is specific to the system's environment, acts upon the wavefunction to yield the wavefunction again, accompanied by the energy of the system (the eigenvalue). Postulate V states that the time-dependant Schrödinger equation (1) describes the evolution of a system’s wavefunction through time.

\[\hat{H}\Psi_(x,t) = {i}\hbar \dfrac{\partial\Psi}{\partial{t}} \tag{1}\]

For a time-independent Hamiltonian Operator, this assumption allows separation of variables:

\[\Psi _{(x,t)} =\psi _{(x)} \cdot f_{(t)} \tag{2}\]

Equation (2) is substituted into equation (1).

\[\hat{H}\psi _{(x)}\cdot f_{(t)} = i\hbar \displaystyle\frac{d\psi _{(x)} \cdot f_{(t)}}{dt} \tag{3} \]

Equation (3) is then manipulated so the left side is explicitly in terms of \(x\), while the right side only in terms of \(t\).

\[\displaystyle\frac{1}{\psi _{(x)}} {\hat{H}_{(x)}} \psi _{(x)} =\displaystyle\frac{1}{f_{(t)} } i\hbar \displaystyle\frac{df_{(t)} }{dt} \tag{4}\]

If both sides (dependent upon different variables) are to be equal, they must both equal the same constant. We shall call this constant E. The left side becomes equivalent to the time-independent Schrödinger equation:

\[{\hat{H}} \Psi _{(x)} =E\Psi _{(x)} \tag{5} \]

The right side becomes:

\[ {\displaystyle\frac{df_{(t)}}{dt}} =\displaystyle\dfrac{-i}{\hbar } E\cdot f_{(t)} \tag{6}\]

Equation (6) is manipulated into equation (7) and then integrated:

\({\displaystyle\frac{df_{(t)}}{f_{(t)}}} =\displaystyle\dfrac{-i}{\hbar } E\cdot {dt}\)

\[\displaystyle\int \frac{df_{(t)} }{f_{(t)} } =\frac{-i}{\hbar } E\cdot \int {dt} \tag{7}\]

\[ f_{(t)} =\displaystyle{e^{(-\frac{iE\cdot {t}}{\hbar })}} \tag{8} \]

Since \(E=hv=\hbar\omega\), this is also equal to:

\[ f_{(t)} =e^{(-i \cdot {\omega} \cdot {t})} \tag{9}\]

Equations (9) now plugged into equation (2) give the solution to the time-dependant Schrödinger equation:

\[\Psi _{(x,t)} =\psi _{(x)} \cdot e^{(-i\cdot {\omega}\cdot {t})} \tag{10}\]

An example of the time dependence of a localized particle in a box can be seen below. First, the constants have to be defined:

- a=1
- h=1
- m=1
- \(i=\sqrt{-1}\)

Using these constants, the wavefunction and energy solutions can be found:

\[E(n)=\dfrac{h^2}\cdot{n^2}} {8\cdot{m}\cdot{a^2}}\]

\(\omega{(n)}=\dfrac{2 \pi E_n}{h}\)

\psi{(n,x,t)}=\sqrt{\dfrac{2}{a}}{sin\left(\dfrac{n \pi x}{a}\right)}\cdot{e^{-i \omega{(n)}t}}

The particle can then be localized by superpositioning the wavefunctions:

\(n_{max}=4\) \(n=1,2...n_{max}\)

\(\Psi{(x,t)}=\displaystyle\sum_{n}\dfrac{1}{\sqrt{n_{max}}}\cdot\psi{(n,x,t)}\)

\(P(x,t)=\Psi{(x,t)}\cdot{\Psi{(x,t)}}\)

Using these values and definitions, the following plots of wavefunctions, superposed wavefunctions, and probability distributions can be found (attached below). These plots are captioned to show whether they are real or imaginary and the time.

- For t=0, there is no imaginary part for the wavefunction, superpsed wavefunctions, and therefore, the probability distribution function.
- For all probability distribution functions, there is no imaginary portion since i
^{2}= -1.

Real portion of wavefunctions at t=0

Real portion of superposed wavefunctions at t=0

Real portion of probability distribution at t=0

Real portion of wavefunctions at t=1

Real portion of superposed wavefunctions at t=1

Real portion of probability distribution at t=1

Imaginary portion of wavefunctions at t=1

Imaginary portion of superposed wavefunctions at t=1

Real portion of wavefunctions at t=2

Real portion of superposed wavefunctions at t=2

Real portion of probability distribution at t=2

Imaginary portion of wavefunctions at t=2

Imaginary portion of superposed wavefunctions at t=2

- Quantum Chemistry 2nd Edition; McQuarrie, Donald A.; University of California, Davis; Sausolito.(2008).

- Eric Gobrogge (Hope College), Alex Ketchum (Hope College)

Last modified

08:32, 31 Jul 2014

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This material is based upon work supported by the National Science Foundation under Grant Number 1246120

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