GeoWiki.png
ChemWiki: The Dynamic Chemistry E-textbook > Physical Chemistry > Quantum Mechanics > Quantum Theory > De Broglie Wavelength

De Broglie Wavelength

Deriving the De Broglie Wavelength

De Broglie derived his equation using well established theories through the following series of substitutions:

1. De Broglie first used Einstein's famous equation relating matter and energy:

\[ E = mc^2 \]

with

  • \(E\) = energy,
  • \(m\) = mass,
  • \(c\) = speed of light

2. Using Planck's theory which states every quantum of a wave has a discrete amount of energy given by Planck's equation:

\[ E= h \nu\]

with

  • \(E\) = energy,
  • \(h\) = Plank's constant (6.62607 x 10-34 J s),
  • \(\nu\)= frequency

3. Since de Broglie believed particles and wave have the same traits, he hypothesized that the two energies would be equal:

\[ mc^2 = h\nu\]

4. Because real particles do not travel at the speed of light, De Broglie submitted velocity (\(v\)) for the speed of light (\(c\)).

\[ mv^2 = h\nu \]

5. Through the equation \(\lambda\), de Broglie substituted \( v/\lambda\) for \(\nu\) and arrived at the final expression that relates wavelength and particle with speed.

\[ mv^2 = \dfrac{hv}{\lambda} \]

Hence:

\[ \lambda = \dfrac{hv}{mv^2} = \dfrac{h}{mv} \]

Although De Broglie was credited for his hypothesis, he had no actual experimental evidence for his conjecture. In 1927, Clinton J. Davisson and Lester H. Germer shot electron particles onto onto a nickel crystal. What they see is the diffraction of the electron similar to waves diffraction against crystals (x-rays). In the same year, an English physicist, George P. Thomson fired electrons towards thin metal foil providing him with the same results as Davisson and Germer.

A majority of Wave-Particle Duality Problems are simple plug and chugs with some variation of canceling out units

Example 1

Find the de Broglie wavelength for an electron moving at the speed of 6.63 x 106 m/s (mass of an electron = 9.1 x 10-31 kg).

SOLUTION

You must to post a comment.
Last Modified
09:03, 7 Feb 2014

Page Rating

Was this article helpful?

Tags

Module Vet Level:
Module Target Level:

Creative Commons License UC Davis GeoWiki by University of California, Davis is licensed under a Creative Commons Attribution-Noncommercial-Share Alike 3.0 United States License. Permissions beyond the scope of this license may be available at copyright@ucdavis.edu. Terms of Use