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ChemWiki: The Dynamic Chemistry E-textbook > Physical Chemistry > Thermodynamics > State Functions > Enthalpy > Heat of Fusion

Heat of Fusion

In a chemical reaction, solids can be heated to the point where the molecules holding their bonds together break apart and form a liquid. The most common example is solid ice turning into liquid water. This process is better known as melting, or heat of fusion, and results in the molecules within the substance becoming more chaotic. When a substance converts from a solid state to a liquid state, the change in heat (ΔH) is positive. However, if the substance is transforming from a liquid state to a solid state the change in heat (ΔH) is negative. This process is commonly known as the freezing, and results in the molecules within the substance becoming more ordered.

Introduction

Determining the heat of fusion is fairly straightforward. When a solid undergoes melting or freezing, the temperature stays at a constant rate until the entire phase change is complete. One can visualize this process by examining the heating/cooling chart . By drawing this chart before conducting a heat of fusion analysis, one can easily map out the required steps in completing the analysis. The equation for determining the heat change of fusion (ΔH) is listed below.

\[\Delta{H}=n \,\Delta{H_{fus}}\]

with

  • \(n\)= number of moles
  • \(\Delta{H_{fus}}\) the molar heat of the substance

 

Example 1

Calculate the change in heat when 36.0 grams of water at 113 °Celsius is cooled to 0 °Celsius.

SOLUTION

Heat of fusion= 6.0 kJ/mol
Heat of vaporization= 40.7 kJ/mol

Csp(s)=2.01 J/gK
Csp(l)=4.18 J/gK
Csp(g)=1.97 J/gK

Answer=ΔHtotal=-110.6 KJ

Sublimation

In some cases, the solid will bypass the liquid state and transition into the gaseous state. This direct transformation from solid to gas is called sublimation. The opposite reaction, when a gas directly transforms into a solid, is known as deposition. Therefore, these two processes can be summarized in the following equation:

\[\Delta{H_{sub}}= \Delta{H_{fux}}+\Delta{H_{vap}}\]

with

  • ΔHsub = change in heat sublimation
  • ΔHfus = change in heat fusion
  • ΔHvap = change in heat vaporization

Important things to remember about Heat of Fusion

The units for ΔH fusion are kilojoules/mol. Freezing and melting points are the nearly the same. The only difference is the sign in front of the value. Freezing has a negative ΔH value, and heat of fusion/melting has a positive ΔH value. One can find more change in heat of fusion (ΔH) values in table 12.4 or Appendix D in the chemistry textbook.

Applications

The heat of fusion process can be seen in countless applications and evidenced in the creation of many common household items. As mentioned in the opening paragraph, the most common application of the heat of fusion is the melting of ice to water. The vast majority of examples where heat of fusion is commonplace can be seen in the manufacturing industry. The following examples have been used for hundreds of years and are still perfected to this day. The processes of coin making, glassblowing, forging metal objects, and transforming blow molded plastics into household products all require heat of fusion to become final product. The change in your wallet, the glass vase on your fireplace mantel, and the plastic soda bottle from the vending machine all went through a heat of fusion manufacturing process.

In coin making, solid zinc and copper (metals in American pennies) are placed into a casting furnace and heated by the heat of fusion process until they reach the liquid phase. Once in the liquid phase, the molten zinc and copper are poured into a mold, and cast into long bars. In the casting process, the molten metal transforms from the liquid phase to the solid phase, becoming a solid bar. The long bars are flattened by heavy machinery and stamped into thousands of coins. Without the heat of fusion process, a monetary system would not exist in the United States.

References

  1. Haydon, Julie. Making Coins and Bills. Smart Apple Media, 2006.
  2. Hill, John William. General Chemistry : An integrated Approach. Prentice Hall, 1933-2002.
  3. Petrucci, Ralph H., et al. General Chemistry: Principles & Modern Applications. 9th ed. Upper Saddle River, New Jersey 2007.
  4. Hagenbaugh, Barbara. Mint Considers Changes in Change ; Soaring Metal Costs Could Lead to New Coin Makeup. pg. B.1. McLean, VA: USA Today, Aug 9, 2007.
  5. Khoshmanesh, Kh. Numerical Simulation and Experimental Analysis of an Industrial Glass Melting Furnace. Vol. 28 Issue 5/6, p450-459. April 2008.

Contributors

  • Maxim Hnojewyj (UCD)

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Last Modified
20:54, 7 Jul 2014

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