Interesting online CONFCHEM discussion going on right now on the ChemWiki and
greater STEMWiki Hyperlibary project. Come join the discussion.
|Both dishes contain a solution of HCl, 3% H2O2, and KSCN. |
The solution in the dish containing the lone nail turns a pink color, and the intensity of the color increases over time. In the dish containing the nail/zinc metal connection, a gas is produced on the surface of the metal, but the pink color does not appear. When the connection between the nail and the zinc metal is severed, the solution begins to turn pink.
The pink coloration is due to the formation of Fe(SCN)2+/Fe(SCN)2+ complexes. This indicates that the iron metal is being oxidized to the Fe3+ ion. This won't occur in the second dish as long as the nail is connected to the zinc metal strip. When the two metals are connected, the zinc undergoes oxidation to Zn 2+ at the same time that H + ions are reduced to H2on the surface of the iron nail.
This material is based upon work supported by the National Science Foundation under Grant Number 1246120