If you like us, please share us on social media or tell your professor. Consider building or adopting a Wikitext for your course like Prof. Dianne Bennett from Sacramento City College demonstrates in this video.

ChemWiki: The Dynamic Chemistry Hypertext > Under Construction > Virtual > Virtual: Molecular Orbitals > Overlap of Atomic Orbitals

Overlap of Atomic Orbitals

- For any pair of atomic orbitals on two atoms, determine whether there is no interaction or a net interaction between the two orbitals.
- For orbitals where a net interaction occurs, determine whether the interaction produces sigma, pi, or delta bonding/antibonding orbitals.

Use the controls on the left to select the orbital on the left atom and the orbital on the right atom. Then use the controls to move the orbitals close together so that overlap occurs. Carefully examine the overlap and determine whether the two orbitals interact (bonding/antibonding orbitals are formed) or do not interact (orbitals are nonbonding).

The green color represents an area where the wave function has a positive sign; the red color represents an area where the wave function has a negative sign.

**NOTE:** In this exercise, the two atoms approach each other along the z-axis. In other molecules, especially molecules containing more than two atoms, atoms may approach from other directions, and consequently the orbitals that interact will differ from those in this example. For this reason, do **not** attempt to memorize orbital combinations; it is necessary to examine the overlap behavior for each molecule individually.

It is possible to examine all 45 combinations of orbitals (3s, 3p_{x}, 3p_{y}, 3p_{z}, 3d_{z2}, 3d_{xz}, 3d_{yz}, 3d_{xy}, and 3d_{x2-y2}). For the purpose of this exercise, however, it is only necessary to examine the following combinations:

- 3s and 3p
_{z} - 3s and 3p
_{y} - 3p
_{x}and 3p_{y} - 3s and 3d
_{z2} - 3p
_{y}and 3d_{yz} - 3p
_{y}and 3d_{xy} - 3d
_{yz}and 3d_{yz} - 3d
_{xy}and 3d_{xy} - 3s and 3d
_{yz} - 3d
_{x2-y2}and 3d_{x2-y2}

Display the 3p_{y} orbital on the left atom, and systematically examine the overlap of this orbital with all possible orbitals on the right atom (there are nine orbitals). For each pair of orbitals, indicate whether there the orbitals are nonbonding (n), sigma bonding/antibonding (σ/σ^{*}), pi bonding/antibonding (π/π^{*}), or delta bonding/antibonding (δ/δ^{*}).

- David Blauch (Davidson College)

Last modified

09:40, 2 Oct 2013

- © Copyright 2016 Chemwiki

Unless otherwise noted, content in the UC Davis ChemWiki is licensed under a Creative Commons Attribution-Noncommercial-Share Alike 3.0 United States License. Permissions beyond the scope of this license may be available at copyright@ucdavis.edu. Questions and concerns can be directed toward Prof. Delmar Larsen (dlarsen@ucdavis.edu), Founder and Director. Terms of Use