• Chem110B Extra Creditv
  • Butadiene is Stabilized by a Delocalization Energy
  • Conjugated Hydrocarbons and Aromatic Hydrocarbons Can Be Treated by a Pi-Electron Approximation
  • Different Hybrid Orbitals Are Used for the Bonding Electrons and the Lone Pair Electrons in Water
  • Different Regions of the Electromagnetic Spectrum Are Used to Investigate Different Molecular Processes
  • Electronic Spectra Contain Electronic, Vibrational, and Rotational Information
  • Hybrid Orbitals Account for Molecular Shape
  • Overtones Are Observed in Vibrational Spectra
  • Rotational Transitions Accompany Vibrational Transitions
  • Selection Rules Are Derived from Time-Dependent Perturbation Theory
  • Symmetry Operations Can Be Represented by Matrices
  • The Boltzmann Factor Is One of the Most Important Quantities in the Physical Sciences
  • The C3V Point Group Has a Two-Dimensional Irreducible Representation
  • The Franck-Condon Principle Predicts the Relative Intensities of Vibronic Transitions
  • The Harmonic-Oscillator Selection Rule Is Δv = ±1
  • The Heat Capacity at Constant Volume Is the Temperature Derivative of the Average Energy
  • The Lines in a Pure Rotational Spectrum Are Not Equally Spaced
  • The Most Important Summary of the Properties of a Point Group Is Its Character Table
  • The Probability That a System in an Ensemble Is in the State j with Energy Ej (N,V) Is Proportional to e-Ej(N,V)/kBT
  • The Rotational Spectrum of a Polyatomic Molecule Depends Upon the Principal Moments of Inertia of the Molecule
  • The Selection Rule in the Rigid Rotator Approximation Is ΔJ = ±1
  • The Symmetry Operations of a Molecule Form a Group
  • Vibration-Rotation Interaction Accounts for the Unequal Spacing of the Lines in the P and R Branches of a Vibration-Rotation Spectrum
  • We Postulate That the Average Ensemble Energy Is Equal to the Observed Energy of a System

Group theory. Application of quantum mechanics to polyatomic molecules and molecular spectroscopy. Intermolecular forces and the gas, liquid and solid states. Distributions, ensembles and partition functions. Transport properties.

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