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Inorganic Chemistry: Fundamentals (CHE 124A) Instructor: Susan Kauzlarich
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Module Topic Name Select only ONE Primary Module Name Select THREE Secondary Modules (Max of three per Primary Module) Name Select only ONE Tertiary Module from YOUR selected Secondary Modules Fundamental Particles of Atoms Nuclide, Atomic Number, mass number Relative Atomic Mass Isotopes Bohr's Hydrogen Atom Wave Mechanics of electrons The Uncertainty Principle Atomic Orbitals Quantum Numbers: n,l,ml Radial Wavefunction R(r) Radial distribution function 4π r2 R(r) Angular Wavefunction A(θ,φ) Orbital Energies Size of Orbitals Spin Quantum Number, ms The ground state of Hydrogen The Helium Atom Ground state electronic Configuration Penetration and Shielding Periodic Table Valence and Core Electrons Diagrammatic Representations of electron configurations Ionzation Energies and Electron Affinities Lewis Structures Overview of Valence Bond Theory Covalent Bond Distance, Radius and van der Waals Radius Valence Bond model of Bonding in H2 Valence Bond model of bonding in F2 , O2 , and N2 Overview of Molecular Orbital Theory MO theory of bonding in H2 MO bonding in He2 , Li2 and Be2 MO bonding in F2 and O2 Small S-P energy Separation Effects Octet Rule: first row p-block elements Isoelectronic Species Octet Rule: Heavier p-block elements Pauling Electronegativity Mulliken Electronegativity Allred-Rochow Electronegativity Dipole Moments Molecular Dipole Moments MO Theory: Orbital Interactions MO Theory: HF MO Theory: CO VSEPR Trigonal Bipyramidal Structures Limitations of VSEPR Molecular Shape: Stereoisomerism Square Planar Species Octahedral Species Trigonal Bipyramidal Species High Coordination Numbers Double Bonds Symmetry Operations (all) and Elements Successive Symmetry Operations Point Groups C1 Point Group C∞ v Point Group D∞h Point Group Td , Oh and Ih Point Groups Determining the Point Group of a molecule Character Table Benefits of recognizing Symmetry Vibrational Spectroscopy Number of vibrational modes for a molecule ATR-FTIR Selection Rules for IR and Raman active modes Vibrational Spectroopy of Linear and Bent triatomic Molecules Bent Molecules XY2 : using the C2 Character table XY3 molecules with D3h Symmetry XY3 molecules with C3v Symmetry XY4 molecules with Td or D4h Symmetry XY6 molecules with Oh Symmetry Metal Carbonyl Complexes (M(CO)n Metal Carbonyl Complexes M(CO)6-n IR spectropscopy: Practical Problems Chiral Molecules Orbital hybridization sp Hybridization sp 2 sp3 Hybridization Other Hybridization schemes Valence Bond Theory: Multiple Bonding in polyatomic molecules Valence Bond Theory: C2 H4 Valence Bond Theory: HCN Valence Bond Theory: BF3 MO Application: polyatomic molecules MO Application: linear XH2 : Symmetry by examination MO Application: linear XH2 : working from a molecular symmetry Bent triatomic: H2 O Molecular Orbital Theory applied to BH3 Molecular Orbital Theory applied to NH3 Molecular Orbital Theory applied to CH4 Contrasting MO and VB theory Molecular Orbital Theory: Complications MO Theory: Objective Aplications MO Theory: π- Bonding in CO2 MO Theory: [NO3 ]- MO Theory: SF6 The center two-electron interactions MO Theory:B2 H6 Cubic and Hexagonic close-packing The Unit Cell Intersitial Holes Non-close-packing Group 18 Elemental Solids H2 and F2 Solids Solid Metallic Elements Polymorphism Phase Diagrams metallic radii Melting Points and Enthalpies of Atomization Substitutional Alloys Interstitial Alloys Intermetallic Compounds Electrical Conductivity and Resistivity Band Theory of Metals and Insultators Fermi level Band Theory of Semiconductors Intrinsic Semiconductors Extrinsic Semiconductors Ionic Radii Periodic Trends in Ionic Radii Structure: Rock Salt Structure: CsCl Structure: CaF2 Structure: Antifluorite Structure: Zinc Blend Structure: SiO2 Structure: ZnS Structure: TiO2 (rutile) Structure: CdI and CdCl2 Structure: Perovskite (CaTiO3 ) Crystal Structures of Semiconductors Coulombic Attraction Coulombic Attraction in a lattice Born Forces The Born-Lande' equation Madelung Constants Refined Born-Lande' equation Lattice Energy: The Born-Haber cycle Lattice Energy: Experimental vs. Calculated values Estimating Lattice Energies Fluoride Affinities Enthalpies of Formation and Disproportionation The Kapustinskii Equation Schottky Defect Frenkel Defect Evidence of Schottky and Frenkel Defects
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